850 is barely enough for 580 SLI.(no OC headroom)
750v2 can possibly power it,but it is borderline with little room for OCing.
Get 850W for 570 SLI and 950-100W for 580 SLI.
the 750 is a great model so it can handle it,but i would always avoid peaking the power draw.
@nginx: Very much second this...
If you have a budget of above 100K, u should not skimp on the PSU...
I think u should get minimum HX1000 or HX1050...for 580 SLI....it will cost 5K more than what (it seems) u have currently allocated to the PSU but in the long run, this will be worth it... Have a look
here or
here
Then again, I think u said u might even go 590 SLI sometime in future, in which case I think ur best candidate would be the AX1200 @18K approx.