Nope sorry pal....ur Vcd could just support The Vcd Movie files....may be the Audio Discs and Also to some extent the Mp3 files.....but a sure no no to those multimedia discs....
btw a DVD player could also support .jpg Photo discs at the most but they too cant read this discs unless coded in the formats specified to be played....also what does this multimedia disc of urs contain...if they are .mpg files then u can have em burned on a separate disc via nero using the VCD option and then possibly it might play the video files...besides this aint a DVD-Rom boss just a DVD player which is meant for movie,music and photo viewing and not Pc's data disc readin purposes