Well this is certainly possible,i had done this to power my grafix cards.
I had a powersafe 500W which proved insufficient for my system so added another 350W one to just give juice to the 2 grafix cards.
The problem is that with this trick,the auxillary PSU starts before you start teh system,personally i am not comfortable with this as i prefer to see both the PSUs starting at the same time.
I am trying to find a solution for this as i am gonna do this again,i will let you know,what i do to solve this problem.