Playing 4K directly on a Dual Core NAS is a hit or miss. Imagine watching your favorite video on 4K and getting a buffer screen all of a sudden in between. Would you like it ? It will spoil your 4K watching experience right. So, you will have to manage your content viewing cautiously, and what I mean by that is you will have to tell your family/friends....
"Don't stream anything right now....as I am watchin 4K. And if you do that would stress my Dual core NAS CPU" and that could also include your relatives connecting to your NAS from remote.
So, would you blame your decision of not buying a Quad Core CPU for 4K ? just like we say in hindi
"Isse accha toh mai Quad Core le leta..."
The 4K content you will watch will not just include mkv/mp4 files of Movies/Series, it might also include your handycam/camera videos in 4K (if you shoot it now or in future)