if u wanna learn ASP.net refer to the book ASP.Net 3.0 Begineers of Wronx Publications its a great book. and then go for advance and security book of the same.
ya u can use them to create softwares but do buy a original package if u are starting working with it as it will provide some small additions in it. and never gives the problem in case it corrupts and u reinstall it as i have experienced.....
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